Substrate placing table and substrate processing apparatus

ABSTRACT

A substrate placing table according to an exemplary embodiment includes a base and an electrostatic chuck provided on the base. The electrostatic chuck includes a lamination layer portion, an intermediate layer, and a covering layer. The lamination layer portion is provided on the base. The intermediate layer is provided on the lamination layer portion. The covering layer is provided on the intermediate layer. The lamination layer portion includes a first layer, an electrode layer, and a second layer. The first layer is provided on the base. The electrode layer is provided on the first layer. The second layer is provided on the electrode layer. The intermediate layer is provided between the second layer and the covering layer and is in close contact with the second layer and the covering layer. The second layer is a resin layer. The covering layer is ceramics.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a Continuation of U.S. patent application Ser. No. 16/721,086 filed Dec. 19, 2019, which is based on and claims the benefit of priority from Japanese Patent Application Nos. 2018-244752 and 2019-203311 filed on Dec. 27, 2018 and Nov. 8, 2019, respectively, with the Japan Patent Office, the entire contents of which are incorporated herein by reference.

TECHNICAL FIELD

Exemplary embodiments of the present disclosure relate to a substrate placing table and a substrate processing apparatus.

BACKGROUND

A substrate (wafer) placed on a placing table can be held by an electrostatic chuck. The electrostatic chuck electrostatically attracts the wafer to the placing table by an electrostatic force. A placing device disclosed in Japanese Unexamined Patent Publication No. 2008-117982 is provided with a placing body and an electrostatic chuck. An object to be treated is placed on the placing body. The electrostatic chuck is provided with an insulating layer and an electrode layer embedded in the insulating layer. In the electrostatic chuck, voltage is applied to the electrode layer, whereby an electrostatic force is generated between the electrode layer and the object to be treated, and thus the object to be treated is electrostatically attracted to the surface of the insulating layer. An electrostatic chuck layer which is an insulating layer on the surface side of the electrode layer is an yttrium oxide sprayed layer having a thickness in a range of 200 to 280 μm and formed by plasma spraying. The surface of the electrostatic chuck layer is formed with a surface roughness depending on the particle size of yttrium oxide which is thermally sprayed.

SUMMARY

In an exemplary embodiment, a substrate placing table is provided. The substrate placing table includes a base and an electrostatic chuck provided on the base. The electrostatic chuck includes a lamination layer portion, an intermediate layer, and a covering layer. The lamination layer portion is provided on the base. The intermediate layer is provided on the lamination layer portion. The covering layer is provided on the intermediate layer. The lamination layer portion includes a first layer, an electrode layer, and a second layer. The first layer is provided on the base. The electrode layer is provided on the first layer. The second layer is provided on the electrode layer. The intermediate layer is provided between the second layer and the covering layer and is in close contact with the second layer and the covering layer. The second layer is a resin layer. The covering layer is ceramics.

The foregoing summary is illustrative only and is not intended to be in any way limiting. In addition to the illustrative aspects, exemplary embodiments, and features described above, further aspects, exemplary embodiments, and features will become apparent by reference to the drawings and the following detailed description.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a diagram showing an example of a configuration of a substrate placing table according to an exemplary embodiment.

FIG. 2 is a diagram showing an example of a configuration of an end portion of the substrate placing table shown in FIG. 1.

FIG. 3 is a diagram showing an example of a configuration of a part of the substrate placing table shown in FIG. 1.

FIG. 4 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 5 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 6 is a diagram for explaining a method of forming a covering layer shown in each of FIGS. 2 to 5.

FIG. 7 is a diagram showing an example of a configuration of a substrate processing apparatus provided with the substrate placing table shown in FIG. 1.

FIG. 8 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 9 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 10 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 11 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 12 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 13 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 14 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 15 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 16 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 17 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 18 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 19 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 20 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 21 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 22 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 23 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

FIG. 24 is a diagram showing another example of the configuration of the end portion of the substrate placing table shown in FIG. 1.

DETAILED DESCRIPTION

In the following detailed description, reference is made to the accompanying drawings, which form a part hereof. The exemplary embodiments described in the detailed description, drawing, and claims are not meant to be limiting. Other exemplary embodiments may be utilized, and other changes may be made, without departing from the spirit or scope of the subject matter presented here.

The present disclosure provides a technique for suppressing an electric discharge between a substrate placing table and a substrate.

Hereinafter, various exemplary embodiments will be described. In an exemplary embodiment, a substrate placing table is provided. The substrate placing table includes a base and an electrostatic chuck provided on the base. The electrostatic chuck includes a lamination layer portion, an intermediate layer, and a covering layer. The lamination layer portion is provided on the base. The intermediate layer is provided on the lamination layer portion. The covering layer is provided on the intermediate layer. The lamination layer portion includes a first layer, an electrode layer, and a second layer. The first layer is provided on the base. The electrode layer is provided on the first layer. The second layer is provided on the electrode layer. The intermediate layer is provided between the second layer and the covering layer and is in close contact with the second layer and the covering layer. The second layer is a resin layer. The covering layer is ceramics. Since it is known that the second layer provided on the electrode layer of the electrostatic chuck in this manner has a relatively high insulation resistance as resin, it is possible to sufficiently reduce the thickness of the second layer while maintaining a predetermined insulation resistance. Therefore, the combined electrostatic capacity of the electrostatic chuck can be increased, and thus the potential between the substrate placed on the substrate placing table and the base can be reduced. For this reason, when voltage is applied to the substrate placing table at a relatively low frequency, a voltage phase difference is reduced, whereby the generation of an electric discharge between the substrate placing table and the substrate can be suppressed.

In the exemplary embodiment, the first layer is a resin layer.

In the exemplary embodiment, the base includes a main body part and a side wall part provided on a side surface of the base. The electrostatic chuck is disposed on the main body part and the side wall part. A diameter of each of the first layer and the second layer is larger than a diameter of the main body part. The first layer and the second layer extend on the base to overlap the side wall part.

In the exemplary embodiment, the intermediate layer includes an end portion region that covers a side surface of the lamination layer portion. The end portion region is in contact with the base and has a tapered shape that is tapered in a direction separated from the lamination layer portion.

In the exemplary embodiment, a taper angle of the end portion region is 45° or less.

In the exemplary embodiment, a material of the first layer and a material of the second layer are any one of polyimide resin, silicone resin, epoxy resin, and acrylic resin.

In the exemplary embodiment, the substrate placing table further includes an end portion region. The end portion region covers a side surface of the lamination layer portion. A material of the end portion region is resin or an insulator. The first layer is an insulating layer or a resin layer.

In the exemplary embodiment, a material of the first layer in a case where the first layer is an insulating layer is ceramic. A material of the first layer in a case where the first layer is a resin layer is any one of polyimide resin, silicone resin, epoxy resin, and acrylic resin. A material of the second layer is any one of polyimide resin, silicone resin, epoxy resin, and acrylic resin.

In the exemplary embodiment, the end portion region made of resin has a tapered shape that is tapered in a direction separated from the lamination layer portion.

In the exemplary embodiment, the base has an insulating region on a surface of the base. The insulating region has a portion extending along a side surface of the lamination layer portion. The end portion region made of resin is provided between the side surface of the lamination layer portion and the portion of the insulating region.

In the exemplary embodiment, the base includes a main body part and a side wall part provided on a side surface of the base. The electrostatic chuck is disposed on the main body part and the side wall part. An inner diameter of each of the first layer and the second layer is smaller than an inner diameter of the main body part. The first layer and the second layer extend on the base to overlap the side wall part. A surface of the side wall part has a portion extending along a side surface of the lamination layer portion. The end portion region made of resin is provided between the side surface of the lamination layer portion and the portion of the surface of the side wall part.

In the exemplary embodiment, a diameter of the electrode layer is smaller than a diameter of each of the first layer and the second layer.

In the exemplary embodiment, the intermediate layer covers an entire surface of the lamination layer portion provided on the base.

In the exemplary embodiment, the intermediate layer covers a part of the side wall part.

In the exemplary embodiment, the covering layer includes a foundation layer and a plurality of protrusion portions. The foundation layer is in close contact with the intermediate layer. The plurality of protrusion portions are provided on an upper surface of the foundation layer.

In the exemplary embodiment, a surface roughness of the upper surface of the foundation layer is in a range of 0.05 to 0.5 μm.

In the exemplary embodiment, the intermediate layer includes a base body and a plurality of granules dispersed in the base body. The plurality of granules include exposed portions exposed from the base body, and the exposed portions are in contact with the second layer and the covering layer.

In the exemplary embodiment, a material of the base body contains resin or a silane-based agent, and a material of the granule is ceramic. The silane-based agent is, for example, an inorganic material containing silicon atoms and oxygen atoms.

In an exemplary embodiment, a substrate processing apparatus is provided. The substrate processing apparatus includes any one of the substrate placing tables described above.

The substrate processing apparatus according to the exemplary embodiment includes a radio frequency power source, and the radio frequency power source is connected to the substrate placing table and supplies radio frequency power of 3 MHz or less to the substrate placing table.

Hereinafter, various exemplary embodiments will be described in detail with reference to the drawings. In each drawing, identical or equivalent parts are denoted by the same reference numerals. First, an embodiment of the configuration of a substrate placing table 2 will be described with reference to FIG. 1.

The substrate placing table 2 is provided in a substrate processing apparatus 1. The substrate processing apparatus 1 can be, for example, a parallel plate type plasma processing apparatus, but is not limited thereto. The substrate processing apparatus 1 is sufficiently provided with devices necessary for plasma processing on a substrate (hereinafter, there is a case where it is referred to as a wafer) placed on the substrate placing table 2. However, details of the configuration of the substrate processing apparatus 1 are not shown in FIG. 1. The details of the configuration of the substrate processing apparatus 1 will be described later with reference to FIG. 7.

The substrate placing table 2 has a substantially disk shape extending to intersect a central axis AX. The substrate placing table 2 includes an electrostatic chuck 3 and a base 4. The electrostatic chuck 3 is provided on the base 4. The electrostatic chuck 3 includes a lamination layer portion 3 a, an intermediate layer 3 b, and a covering layer 3 c. The lamination layer portion 3 a is provided on the base 4. The intermediate layer 3 b is provided on the lamination layer portion 3 a. The covering layer 3 c is provided on the intermediate layer 3 b.

The lamination layer portion 3 a includes a layer 3 a 1 (a first layer), an electrode layer 3 a 2, and a layer 3 a 3 (a second layer). The layer 3 a 1 is provided on the base 4. The electrode layer 3 a 2 is provided on the layer 3 a 1. The layer 3 a 3 is provided on the electrode layer 3 a 2. The layer 3 a 3 is a resin layer.

Here, as shown in FIG. 2, the intermediate layer 3 b includes a base body 3 b 1 and a plurality of granules 3 b 2, and the plurality of granules 3 b 2 are dispersed in the base body 3 b 1. Some of the plurality of granules 3 b 2 are exposed from the base body 3 b 1 to the sides of the layer 3 a 3 and the covering layer 3 c (more specifically, a foundation layer 3 c 1), which are in contact with the base body 3 b 1. The plurality of granules 3 b 2 include exposed portions exposed from the base body 3 b 1 in this manner. The exposed portions are in contact with the layer 3 a 3 and the covering layer 3 c. For this reason, the intermediate layer 3 b and the layer 3 a 3, and the intermediate layer 3 b and the covering layer 3 c (more specifically, the foundation layer 3 c 1) are brought into close contact with each other with a strong bonding force, and therefore, the degree of adhesion is improved. The covering layer 3 c includes the foundation layer 3 c 1 and a plurality of protrusion portions 3 c 2. The plurality of protrusion portions 3 c 2 are provided on an upper surface 31 of the foundation layer 3 c 1. In a case where the substrate is placed on the substrate placing table 2, the substrate is in contact with the plurality of protrusion portions 3 c 2.

Description will be made returning to FIG. 1. The intermediate layer 3 b covers the entire surface (including a side surface SF2 of the lamination layer portion 3 a and an upper surface SF3 of the lamination layer portion 3 a) of the lamination layer portion 3 a provided on the base 4. The covering layer 3 c covers the entire surface of the intermediate layer 3 b provided on the base 4.

The intermediate layer 3 b is provided between the layer 3 a 3 and the covering layer 3 c (in particular, the foundation layer 3 c 1). The intermediate layer 3 b is in close contact with the layer 3 a 3 and the foundation layer 3 c 1. The base body 3 b 1 and the granules 3 b 2 are in contact with the foundation layer 3 c 1 and also are in contact with the layer 3 a 3.

A thickness TH1 corresponds to the sum of the thickness of the lamination layer portion 3 a and the thickness of the intermediate layer 3 b. A thickness TH2 corresponds to the thickness of the lamination layer portion 3 a. A thickness TH3 corresponds to the thickness of the covering layer 3 c.

The base 4 includes a main body part 4 a, a side wall part 4 b 1, and a side wall part 4 b 2. The side wall part 4 b 1 and the side wall part 4 b 2 are provided on side surfaces SF1 of the main body part 4 a. The electrostatic chuck 3 is disposed on the main body part 4 a, the side wall part 4 b 1, and the side wall part 4 b 2.

The side wall part 4 b 1 corresponds to the outer wall of the base 4. The side wall part 4 b 2 corresponds to a sleeve that defines a hole GT penetrating the electrostatic chuck 3 and the base 4 in the base 4.

The hole GT can be a hole through which a gas flows, or a hole provided in order to move a pin up and down when placing a wafer W on the substrate placing table 2.

Further, as shown in FIG. 3 as well, the base 4 is provided with a contact pin 4 d. The contact pin 4 d is electrically connected to the electrode layer 3 a 2. In the base 4, the contact pin 4 d is covered with a sleeve 4 c. The configuration shown in FIG. 3 is a configuration which is included in a region ER2 shown in FIG. 1.

The configuration of an end portion of the substrate placing table 2 will be described with reference to FIG. 2. The end portion of the substrate placing table 2 shown in FIG. 2 has a configuration which is included in a region ER1 shown in FIG. 1. The end portion of the substrate placing table 2 is a portion which includes the side wall part 4 b 1 corresponding to the outer wall portion of the base 4, and is a portion which includes the side wall part 4 b 2 corresponding to the sleeve defining the hole GT.

In the end portion of the substrate placing table 2, the intermediate layer 3 b includes an end portion region 3 bb. The end portion region 3 bb covers the side surface SF2 of the lamination layer portion 3 a. The end portion region 3 bb is in contact with the base 4, and more specifically is in contact with the side wall part 4 b 1 and the side wall part 4 b 2.

The end portion region 3 bb has a tapered shape that is tapered in a direction separated from the lamination layer portion 3 a. In other words, the end portion region 3 bb has a thickness that decreases in the direction separated from the lamination layer portion 3 a. The thickness of the end portion region 3 bb decreases substantially linearly in the direction separated from the lamination layer portion 3 a and converges to a thickness TH4.

More specifically, the thickness of the end portion region 3 bb converges to the thickness TH4 at a location separated from the lamination layer portion 3 a approximately by a length LT3. The length LT3 corresponds to the width of a joined portion between the end portion region 3 bb and each of the side wall part 4 b 1 and the side wall part 4 b 2.

The tapered shape of the end portion region 3 bb is not limited to the shape that is tapered substantially linearly, as shown in FIG. 2. For example, the tapered shape of the end portion region 3 bb can be either of a shape tapered with a concave shape (with negative curvature) as in the end portion region 3 bb shown in FIG. 4, or a shape tapered with a convex shape (with positive curvature) as in the end portion region 3 bb shown in FIG. 5.

The diameter of the electrode layer 3 a 2 is smaller than the diameter of each of the layer 3 a 1 and the layer 3 a 3. A length LT1 corresponds to ½ of the difference between the diameter of each of the layer 3 a 1 and the layers 3 a 3 and the diameter of the electrode layer 3 a 2.

The diameter of each of the layer 3 a 1 and the layer 3 a 3 is larger than the diameter of the main body part 4 a. A length LT2 corresponds to ½ of the difference between the diameter of each of the layer 3 a 1 and the layer 3 a 3 and the diameter of the main body part 4 a. In this manner, the layer 3 a 1 and the layer 3 a 3 extend on the base 4 to overlap the side wall part 4 b 1 and the side wall part 4 b 2. The intermediate layer 3 b covers a part of the side wall part 4 b 1 and a part of the side wall part 4 b 2.

According to the substrate placing table 2 having the configuration described above, since the layers 3 a 1 and 3 a 3 sandwiching the electrode layer 3 a 2 of the electrostatic chuck 3 have high insulation resistance, it is possible to sufficiently reduce the thicknesses of the layers 3 a 1 and 3 a 3 while maintaining predetermined insulation resistance. Therefore, the combined electrostatic capacity of the electrostatic chuck 3 can be increased, and thus the potential between the substrate placed on the substrate placing table 2 and the base 4 can be reduced. For this reason, when voltage is applied to the substrate placing table 2 at a relatively low frequency, for example, a frequency of 3 MHz or less, a voltage phase difference is reduced, whereby generation of an electric discharge between the substrate placing table and the substrate can be suppressed.

The electrostatic capacity (combined electrostatic capacity) of the electrostatic chuck 3 is made to be in a range of about 10 to 21 pF/cm². In a case where the electrostatic capacity is smaller than 10 pF/cm², if a radio frequency power of 3 MHz or less is applied to the substrate placing table, an electric discharge between the substrate placing table and the substrate is easily generated. Further, the upper limit value of the electrostatic capacity that is currently possible is 21 pF/cm².

The thickness of the electrode layer 3 a 2 is about 5 μm. The thickness of the layer 3 a 1 is in a range of about 25 to 50 μm. The relative dielectric constant of the layer 3 a 1 is about 3.2. The thickness of the layer 3 a 3 is in a range of about 25 to 50 μm. The relative dielectric constant of the layer 3 a 3 is about 3.2.

The thickness of an adhesion layer 3 a 4 is in a range of about 10 to 20 μm. The relative dielectric constant of the adhesion layer 3 a 4 is about 3.0. The thickness of an adhesion layer 3 a 5 is in a range of about 10 to 20 μm. The relative dielectric constant of the adhesion layer 3 a 5 is about 3.0.

The thickness of the intermediate layer 3 b is in a range of about 20 to 100 μm. The relative dielectric constant of the intermediate layer 3 b is about 2.7. The thickness (the thickness TH3 shown in FIGS. 1 to 5) of the covering layer 3 c is about 65 μm.

The thickness of the foundation layer 3 c 1 is about 50 μm. The relative dielectric constant of the foundation layer 3 c 1 is about 7.1. The thickness of the protrusion portion 3 c 2 is about 15 μm. The relative dielectric constant of the protrusion portion 3 c 2 is about 7.1.

The surface roughness (arithmetic mean roughness: Ra) of the upper surface 31 of the foundation layer 3 c 1 is in a range of 0.05 to 0.5 μm. The surface roughness (arithmetic mean roughness: Ra) of an end surface 32 of the protrusion portion 3 c 2 is in a range of 0.05 to 0.5 μm.

The plurality of protrusion portions 3 c 2 are provided such that, for example, about 20% of the substrate is in contact therewith.

The length LT1 shown in FIGS. 2, 4, and 5 is in a range of about 1.2 to 2.2 mm. The length LT2 shown in FIGS. 2, 4, and 5 is in a range of about 0.7 to 1 mm. In a case where the length LT2 is shorter than 0.7 mm, a leakage current increases at the interface between the ceramics and the layer 3 a 1, and thus an electric discharge easily occurs between the substrate placing table 2 and the substrate. On the other hand, the area of the lamination layer portion 3 a which is in contact with the base 4 is maximized in order to obtain an adsorption force. For this reason, in a case where the length LT2 is longer than 1 mm, the diameter of the main body part 4 a is reduced and the diameter of the ceramics is increased. Therefore, the heat removal area of the base 4 is reduced, so that the temperature of the substrate is locally increased and the temperature in-plane uniformity of the substrate is reduced.

A taper angle θ of the end portion region 3 bb shown in FIG. 2 is, for example, 45° or less.

The layer 3 a 1 shown in each of FIGS. 2 to 6 is, for example, a resin layer. In this case, the material of the layer 3 a 1 and the material of the layer 3 a 3 can be, for example, polyimide resin, silicone resin, epoxy resin, or acrylic resin. The materials of the layer 3 a 1 and the layer 3 a 3 may be different from each other. The covering layer 3 c is ceramics. The material of the side wall part 4 b 1 and the material of the side wall part 4 b 2 are ceramic.

The material of the base body 3 b 1 of the intermediate layer 3 b contains resin or a silane-based agent. The material of the granule 3 b 2 is ceramic.

An example of a method of forming the covering layer 3 c will be described with reference to FIG. 6. The method of forming the covering layer 3 c is not limited to the method shown in FIG. 6 as long as the formation of the protrusion portions 3 c 2 of the covering layer 3 c can be suitably realized.

For the execution of the method shown in FIG. 6, a plasma spraying apparatus for forming the covering layer 3 c made of ceramics by thermal spraying is used. First, a product PD1 is installed in the plasma spraying apparatus. The product PD1 includes the base 4, the lamination layer portion 3 a, and the intermediate layer 3 b. The lamination layer portion 3 a is provided on the base 4, and the intermediate layer 3 b is provided on the lamination layer portion 3 a. The lamination layer portion 3 a includes the layer 3 a 1, the electrode layer 3 a 2, and the layer 3 a 3.

Subsequently, ceramic spraying is performed on the intermediate layer 3 b of the product PD1, so that a product PD2 is formed. In the ceramic spraying, for example, powder of a thermal spray material having a particle diameter of 15 μm or less is sprayed from a tip portion of a nozzle to a plasma generating portion having the axis common with the nozzle together with a plasma generating gas. Subsequently, plasma is generated from the plasma generation gas with an electric power of 50 kW or less in the plasma generation portion, and the sprayed powder of the thermal spray material is liquefied by the plasma and sprayed so as to cover the surface of the intermediate layer 3 b. Since the particle diameter of the powder of the thermal spray material is small and the amount of electric power for melting the powder of the thermal spray material can be reduced, a covering layer 3 d can be formed without burnout of the intermediate layer 3 b during thermal spraying. In the product PD2, the covering layer 3 d is formed on the intermediate layer 3 b by ceramic spraying. The covering layer 3 c shown in FIGS. 1 to 5 is formed by processing the covering layer 3 d.

In the product PD2, the surface of the covering layer 3 d is further polished. Due to this polishing, the surface roughness of the surface of the covering layer 3 d becomes approximately the same as the surface roughness of the upper surface 31 of the foundation layer 3 c 1 shown in FIGS. 1 to 5.

Subsequently, a product PD3 is formed by disposing, for example, a resin mask MK1 having a plurality of opening portions on the covering layer 3 d of the product PD2. The opening portion of the mask MK1 corresponds to a location where the protrusion portion 3 c 2 is provided in the covering layer 3 c shown in FIGS. 1 to 5.

Subsequently, ceramic spraying is further performed on the product PD3 from above the mask MK1 and the covering layer 3 d, so that a product PD4 is formed. The material of ceramics which is used for the formation of the product PD4 is the same as the material of ceramics used for the formation of the covering layer 3 d. In the product PD4, the plurality of opening portions of the mask MK1 are filled with ceramics and a mask MK2 made of ceramic is also formed on the mask MK1. In the product PD4, the locations where the plurality of opening portions of the mask MK1 are filled with ceramic correspond to the protrusion portions 3 c 2 shown in FIGS. 1 to 5.

Subsequently, the mask MK1 and the mask MK2 are removed from the product PD4, so that a product PD5 is formed. In the product PD5, concavities and convexities (the protrusion portion corresponds to the protrusion portion 3 c 2 shown in FIGS. 1 to 5) formed by removing the mask MK1 and the mask MK2 are provided on the surface of the covering layer 3 d.

Subsequently, the end surfaces of the protrusion portions of the covering layer 3 d of the product PD5 are polished, so that the covering layer 3 c is formed from the covering layer 3 d, and the substrate placing table 2 is formed. Due to this polishing, the surface roughness of the end surface of the protrusion portion of the covering layer 3 d of the product PD5 becomes approximately the same as the surface roughness of the end surface 32 of the protrusion portion 3 c 2 shown in FIGS. 1 to 5.

The foundation layer 3 c 1 and the protrusion portions 3 c 2 are formed as described above, whereby not only the surface roughness of the end surface 32 of the protrusion portion 3 c 2 but also the surface roughness of the upper surface 31 of the foundation layer 3 c 1 is reduced. For this reason, for example, when plasma cleaning is performed without placing a substrate, the surface is not easily crushed by the plasma, and therefore, particles which are generated from the foundation layer are sufficiently reduced. The protrusion portion 3 c 2 is not limited to the formation method using a mask, and for example, the protrusion portion 3 c 2 may be formed without using a mask after the surface of the covering layer 3 d of the product PD2 is polished.

An example of the substrate processing apparatus according to an exemplary embodiment will be described with reference to FIG. 7. The substrate processing apparatus 1 is a parallel plate type capacitively coupled plasma processing apparatus and has a substantially cylindrical processing container PC (chamber). An yttrium oxide film is thermally sprayed on the inner surface of the processing container PC, or alumite treatment (anodization) is performed on the inner surface of the processing container PC. The interior of the processing container PC serves as a processing chamber in which plasma processing such as etching processing or film formation processing is performed by plasma. The substrate processing apparatus 1 is provided with the substrate placing table 2 shown in FIGS. 1 to 5.

A semiconductor wafer (hereinafter referred to as a “wafer W”) which is an example of the substrate is placed on the substrate placing table 2. The substrate placing table 2 also functions as a lower electrode.

A direct-current power source 30 is electrically connected to the electrode layer 3 a 2 through the contact pin 4 d (refer to FIGS. 1 and 3). If a direct-current voltage is applied from the direct-current power source 30 to the electrode layer 3 a 2 by the opening and closing of a switch 30 a, the wafer W is attracted to the electrostatic chuck 3 by an electrostatic force.

A focus ring 11 having an annular shape is placed on the outer periphery side of the electrostatic chuck 3 so as to surround an outer edge portion of the wafer W. The material of the focus ring 11 can be, for example, silicon. The focus ring 11 functions to improve the plasma processing efficiency by converging the plasma toward the surface of the wafer W in the processing container PC.

A refrigerant flow path 12 a is formed in the interior of the base 4. A cooling medium (hereinafter also referred to as a “refrigerant”) such as cooling water or brine, for example, output from a chiller 36 flows and circulates through a refrigerant inlet pipe 12 b, the refrigerant flow path 12 a, and a refrigerant outlet pipe 12 c. The substrate placing table 2 made of metal is heat-removed and cooled by the refrigerant circulating in this way.

A heat transfer gas supply source 37 supplies heat transfer gas such as He gas between the front surface of the electrostatic chuck 3 and the back surface of the wafer W through a heat transfer gas supply line 16. With such a configuration, the temperature of the electrostatic chuck 3 is controlled by the refrigerant circulating through the refrigerant flow path 12 a and the heat transfer gas which is supplied to the back surface of the wafer W. In this way, the wafer W is controlled to a predetermined temperature.

A first radio frequency power source 33 that supplies radio frequency power HF for plasma generation having a first frequency is connected to the substrate placing table 2 through a first matching device 33 a. Further, a second radio frequency power source 34 that supplies radio frequency power LF for bias voltage generation having a second frequency is connected to the substrate placing table 2 through a second matching device 34 a. The first frequency is, for example, a radio frequency of 40 MHz, and the first radio frequency power source 33 can supply the radio frequency power HF having the first frequency to the substrate placing table 2. The second frequency is a radio frequency of 3 MHz or less. In the present embodiment, the radio frequency power HF is applied to the substrate placing table 2. However, the radio frequency power HF may be applied to a gas shower head 20.

The first matching device 33 a functions such that the internal impedance of the first radio frequency power source 33 and load impedance apparently coincide with each other when plasma is generated in the processing container PC. The second matching device 34 a functions such that the internal impedance of the second radio frequency power source 34 and load impedance apparently coincide with each other when plasma is generated in the processing container PC.

The gas shower head 20 is mounted so as to close an opening of a ceiling portion of the processing container PC through a shield ring 21 that covers an outer edge portion of the gas shower head 20. A variable direct-current power source 26 is connected to the gas shower head 20, and a negative direct-current voltage (DC) is output from the variable direct-current power source 26. The gas shower head 20 may be made of silicon. The gas shower head 20 also functions as a counter electrode (an upper electrode) facing the substrate placing table 2 (the lower electrode).

A gas introduction port 22 for introducing gas is formed in the gas shower head 20. A gas diffusion chamber 24 a on the center side and a gas diffusion chamber 24 b on the edge side, which are branched from the gas introduction port 22, are provided in the interior of the gas shower head 20. The gas output from a gas supply source 23 is supplied to the gas diffusion chamber 24 a and the gas diffusion chamber 24 b through the gas introduction port 22, and is diffused in the gas diffusion chamber 24 a and the gas diffusion chamber 24 b and then introduced toward the substrate placing table 2 through a plurality of gas supply holes 25.

An exhaust port 18 is formed in the bottom surface of the processing container PC, and the inside of the processing container PC is exhausted by an exhaust device 38 connected to the exhaust port 18. In this way, the inside of the processing container PC is maintained at a predetermined degree of vacuum. A gate valve 17 is provided on the side wall of the processing container PC. The gate valve 17 is opened and closed when the wafer W is loaded into the processing container PC or unloaded from the processing container PC.

The substrate processing apparatus 1 is provided with a control device 100 that controls the operation of the entire apparatus. The control device 100 includes a CPU 105 (Central Processing Unit), a ROM 110 (Read Only Memory), and a RAM 115 (Random Access Memory). The CPU 105 executes desired plasma processing such as etching according to a recipe stored in a storage area such as the RAM 115. A process time, pressure (gas exhaust), radio frequency power and voltage, various gas flow rates, a temperature in the processing container PC (a temperature of the upper electrode, a side wall temperature of the processing container PC, a temperature of the wafer W, a temperature of the electrostatic chuck 3, or the like), a temperature of the refrigerant from the chiller 36, and the like are set in the recipe.

When plasma processing such as etching or film formation is executed, the opening and closing of the gate valve 17 is controlled, and the wafer W is loaded into the processing container PC and placed on the substrate placing table 2. If a positive or negative direct-current voltage is applied from the direct-current power source 30 to the electrode layer 3 a 2, the wafer W is electrostatically attracted to and held on the electrostatic chuck 3.

At the time of the process, a desired gas is supplied from the gas supply source 23 into the processing container PC, and the radio frequency power HF is applied from the first radio frequency power source 33 to the substrate placing table 2. The radio frequency power LF may be applied from the second radio frequency power source 34 to the substrate placing table 2. A negative direct-current voltage may be applied from the variable direct-current power source 26 to the gas shower head 20. In this way, the gas is separated above the wafer W, so that plasma is generated, and the wafer W is subjected to plasma processing by the action of the plasma.

After the plasma processing, a direct-current voltage having a polarity opposite to that at the time of the electrostatic attraction is applied from the direct-current power source 30 to the electrode layer 3 a 2, and thus the electric charges on the wafer W are discharged. After the discharge of the electric charges, the wafer W is peeled off from the electrostatic chuck 3 and unloaded to the outside of the processing container PC through the gate valve 17.

Modification Examples

Each of FIGS. 8 to 24 shows a modification example of the substrate placing table 2. As the materials of the respective configurations according to the modification examples shown in FIGS. 8 to 24, the materials described above can be adopted unless otherwise specified below.

The modification example shown in FIG. 8 will be described. FIG. 8 is a modification example of the configuration of the substrate placing table 2 in the region ER1 shown in FIG. 1. The substrate placing table 2 has a resin region 3 e as the end portion region, and the base 4 has the main body part 4 a and an insulating region 4 e. The insulating region 4 e corresponds to the side wall part 4 b 1 in the region ER1 shown in FIG. 1. The resin region 3 e is provided on the insulating region 4 e and has a tapered shape that is tapered in a direction separated from the lamination layer portion 3 a. The resin region 3 e is in contact with the side surface SF2 of the lamination layer portion 3 a and the insulating region 4 e and covers the side surface SF2. The insulating region 4 e is provided on the surface of the main body part 4 a. The intermediate layer 3 b covers the layer 3 a 3, the resin region 3 e, and the insulating region 4 e and is in contact with the layer 3 a 3, the resin region 3 e, and the insulating region 4 e. The layer 3 a 1 is a resin layer, and the material of the layer 3 a 1 is, for example, any one of polyimide resin, silicone resin, epoxy resin, and acrylic resin (the same applies to the material of the layer 3 a 1 shown in each of FIGS. 9 to 11 and 14 to 16). The layer 3 a 3 is a resin layer, and the material of the layer 3 a 3 is, for example, any one of polyimide resin, silicone resin, epoxy resin, and acrylic resin (the same applies to the material of the layer 3 a 3 shown in each of FIGS. 9 to 24). The material of the main body part 4 a is, for example, SiC (the same applies to the material of the main body part 4 a shown in FIGS. 9 to 24).

In the configuration shown in FIG. 8, the diameter of the electrode layer 3 a 2 is smaller than the diameter of each of the layer 3 a 1 and the layer 3 a 3, and the intermediate layer 3 b covers the entire surface of the lamination layer portion 3 a provided on the base 4 and covers a part of the side wall part 4 b 2 (the same applies to the configuration of each of FIGS. 9 to 24). Further, in the configuration shown in FIG. 8, the covering layer 3 c includes the foundation layer 3 c 1 and the plurality of protrusion portions 3 c 2, the foundation layer 3 c 1 is in close contact with the intermediate layer 3 b, and the plurality of protrusion portions 3 c 2 are provided on the upper surface 31 of the foundation layer 3 c 1 (the same applies to the configuration of each of FIGS. 9 to 24). Further, in the configuration shown in FIG. 8, the surface roughness of the upper surface 31 of the foundation layer 3 c 1 is in a range of 0.05 to 0.5 μm, and the intermediate layer 3 b includes the base body 3 b 1 and the plurality of granules 3 b 2 dispersed in the base body 3 b 1 (the same applies to the configuration of each of FIGS. 9 to 24). Further, in the configuration shown in FIG. 8, the plurality of granules 3 b 2 include the exposed portions exposed from the base body 3 b 1, and the exposed portions are in contact with the layer 3 a 3 and the covering layer 3 c (the same applies to the configuration of each of FIGS. 9 to 24). Further, in the configuration shown in FIG. 8, the material of the base body 3 b 1 contains resin or a silane-based agent, and the material of the granule 3 b 2 is ceramic (the same applies to the configuration of each of FIGS. 9 to 24).

The modification example shown in FIG. 9 will be described. FIG. 9 is a modification example of the configuration of the substrate placing table 2 in the region ER1 shown in FIG. 1. The substrate placing table 2 has the resin region 3 e and an insulating region 3 f as the end portion regions. The base 4 has the main body part 4 a and the insulating region 4 e. The insulating region 4 e corresponds to the side wall part 4 b 1 in the region ER1 shown in FIG. 1. The resin region 3 e is disposed between the insulating region 3 f and the lamination layer portion 3 a on the insulating region 4 e. The resin region 3 e is in contact with the side surface SF2 of the lamination layer portion 3 a, the insulating region 3 f, and the insulating region 4 e and covers the side surface SF2. The insulating region 3 f is in contact with the insulating region 4 e. The insulating region 4 e is provided on the surface of the main body part 4 a. The intermediate layer 3 b covers the layer 3 a 3, the resin region 3 e, the insulating region 3 f, and the insulating region 4 e and is in contact with the layer 3 a 3, the resin region 3 e, the insulating region 3 f, and the insulating region 4 e. The material of the insulating region 3 f is an insulating material such as aluminum oxide, for example (the same applies to the material of the insulating region 3 f shown in each of FIGS. 11, 15, and 17).

The modification example shown in FIG. 10 will be described. FIG. 10 is a modification example of the configuration of the substrate placing table 2 in the region ER1 shown in FIG. 1. The substrate placing table 2 has the resin region 3 e as the end portion region, and the base 4 has the main body part 4 a and the insulating region 4 e. The insulating region 4 e corresponds to the side wall part 4 b 1 in the region ER1 shown in FIG. 1. The resin region 3 e is provided on the insulating region 4 e, is in contact with the side surface SF2 of the lamination layer portion 3 a and the insulating region 4 e, and covers the side surface SF2. The insulating region 4 e is provided on the surface of the main body part 4 a. The insulating region 4 e has a portion (a protrusion portion 4 e 1) extending along the side surface SF2 of the electrostatic chuck 3. The resin region 3 e is provided between the side surface SF2 of the lamination layer portion 3 a and the protrusion portion 4 e 1 of the insulating region 4 e. The intermediate layer 3 b covers the layer 3 a 3, the resin region 3 e, and the insulating region 4 e and is in contact with the layer 3 a 3, the resin region 3 e, and the insulating region 4 e.

The modification example shown in FIG. 11 will be described. FIG. 11 is a modification example of the configuration of the substrate placing table 2 in the region ER1 shown in FIG. 1. The substrate placing table 2 has the insulating region 3 f as the end portion region, and the base 4 has the main body part 4 a and the insulating region 4 e. The insulating region 4 e corresponds to the side wall part 4 b 1 in the region ER1 shown in FIG. 1. The insulating region 3 f is provided on the insulating region 4 e, is in contact with the side surface SF2 of the lamination layer portion 3 a and the insulating region 4 e, and covers the side surface SF2. The insulating region 4 e is provided on the surface of the main body part 4 a. The intermediate layer 3 b covers the layer 3 a 3, the insulating region 3 f, and the insulating region 4 e and is in contact with the layer 3 a 3, the insulating region 3 f, and the insulating region 4 e.

The modification example shown in FIG. 12 will be described. FIG. 12 is a modification example of the configuration of the substrate placing table 2 in the region ER1 shown in FIG. 1. The substrate placing table 2 has the resin region 3 e as the end portion region, and the base 4 has the main body part 4 a. The lamination layer portion 3 a shown in FIG. 12 has the layer 3 a 1, the adhesion layer 3 a 5 and the electrode layer 3 a 2 provided on the layer 3 a 1, and the layer 3 a 3 provided on the adhesion layer 3 a 5 and the electrode layer 3 a 2. The lamination layer portion 3 a shown in FIG. 12 does not have the adhesion layer 3 a 4 shown in FIG. 8 and the like. The layer 3 a 1 is provided on the main body part 4 a and covers the surface of the main body part 4 a. The resin region 3 e is provided on the layer 3 a 1, is in contact with the side surface SF2 and the layer 3 a 1 of the lamination layer portion 3 a, covers the side surface SF2, and has a tapered shape that is tapered in a direction separated from the lamination layer portion 3 a. The intermediate layer 3 b covers the layer 3 a 3, the resin region 3 e, and the layer 3 a 1 and is in contact with the layer 3 a 3, the resin region 3 e, and the layer 3 a 1. The layer 3 a 1 is an insulating layer or a resin layer (the same applies to the layer 3 a 1 shown in each of FIGS. 13 and 17 to 24). The material of the layer 3 a 1 in a case where the layer 3 a 1 is an insulating film is ceramic, and the material of the layer 3 a 1 in a case where the layer 3 a 1 is a resin layer is any one of polyimide resin, silicone resin, epoxy resin, and acrylic resin. Such a material of the layer 3 a 1 is also the same with respect to the material of the layer 3 a 1 shown in each of FIGS. 13 and 17 to 24.

The modification example shown in FIG. 13 will be described. FIG. 13 is a modification example of the configuration of the substrate placing table 2 in the region ER1 shown in FIG. 1. The base 4 of the substrate placing table 2 shown in FIG. 13 has a conductive region 4 f, and the configuration of the substrate placing table 2 shown in FIG. 13 is different from the configuration of the substrate placing table 2 shown in FIG. 12 in that the conductive region 4 f is provided. The conductive region 4 f is provided on the main body part 4 a and is in contact with the main body part 4 a. The layer 3 a 1 is provided on the conductive region 4 f and is in contact with the conductive region 4 f. The material of the conductive region 4 f is a conductive material such as aluminum or copper (the same applies to the material of the conductive region 4 f shown in each of FIGS. 14 and 21 to 24).

The modification example shown in FIG. 14 will be described. FIG. 14 is a modification example of the configuration of the substrate placing table 2 in the region ER1 shown in FIG. 1. The configuration of the substrate placing table 2 shown in FIG. 14 has the conductive region 4 f, and the configuration of the substrate placing table 2 shown in FIG. 14 is different from the configuration of the substrate placing table 2 shown in FIG. 8 in that the conductive region 4 f is provided. The conductive region 4 f is provided on the main body part 4 a and is in contact with the main body part 4 a. The insulating region 4 e is provided on the conductive region 4 f and is in contact with the conductive region 4 f. The insulating region 4 e corresponds to the side wall part 4 b 1 in the region ER1 shown in FIG. 1.

The configuration shown in FIG. 14 in which the conductive region 4 f is provided is also the same in FIGS. 9 to 11.

The modification example shown in FIG. 15 will be described. FIG. 15 is a modification example of the configuration of the substrate placing table 2 in the region ER1 facing the hole GT. The substrate placing table 2 has the resin region 3 e and the insulating region 3 f as the end portion regions, and a resin region 3 g. The base 4 includes the main body part 4 a and the side wall part 4 b 2 provided on the side surface of the base 4. The electrostatic chuck 3 is disposed on the main body part 4 a and the side wall part 4 b 2. The inner diameter of each of the layer 3 a 1 and the layer 3 a 3 (the diameter of the region including the hole GT and defined by the side surface SF2) is smaller than the inner diameter of the main body part 4 a (the diameter of the region including the hole GT and defined by the side surface SF1). The layer 3 a 1 and the layer 3 a 3 extend on the base 4 so as to overlap the side wall part 4 b 2. The resin region 3 g is provided between the main body part 4 a and the side wall part 4 b 2 and is in contact with the adhesion layer 3 a 4. The resin region 3 g extends so as to expand toward the lamination layer portion 3 a in the vicinity of the lamination layer portion 3 a. The resin region 3 e is in contact with the side surface SF2 of the lamination layer portion 3 a and the side wall part 4 b 2 and covers the side surface SF2. The insulating region 3 f is in contact with the side wall part 4 b 2. The resin region 3 e is disposed between the insulating region 3 f and the lamination layer portion 3 a on the side wall part 4 b 2 and is in contact with the insulating region 3 f and the lamination layer portion 3 a. The intermediate layer 3 b covers the layer 3 a 3 and the resin region 3 e and is in contact with the layer 3 a 3 and the resin region 3 e.

The modification example shown in FIG. 16 will be described. FIG. 16 is a modification example of the configuration of the substrate placing table 2 in the region ER1 facing the hole GT. The substrate placing table 2 has the resin region 3 e as the end portion region, and the resin region 3 g. The base 4 includes the main body part 4 a and the side wall part 4 b 2 provided on the side surface of the base 4. The electrostatic chuck 3 is disposed on the main body part 4 a and the side wall part 4 b 2. The inner diameter of each of the layer 3 a 1 and the layer 3 a 3 (the diameter of the region including the hole GT and defined by the side surface SF2) is smaller than the inner diameter of the main body part 4 a (the diameter of the region including the hole GT and defined by the side surface SF1). The layer 3 a 1 and the layer 3 a 3 extend on the base 4 so as to overlap the side wall part 4 b 2. The resin region 3 g is provided between the main body part 4 a and the side wall part 4 b 2 and is in contact with the adhesion layer 3 a 4. The resin region 3 g extends so as to expand toward the lamination layer portion 3 a in the vicinity of the lamination layer portion 3 a. The surface of the side wall part 4 b 2 has a portion which is in contact with the lamination layer portion 3 a, and a portion extending along the side surface SF2 of the lamination layer portion 3 a (a part of the surface of a protrusion portion 4 b 21 which is included in the side wall part 4 b 2). The resin region 3 e is provided between the side surface SF2 of the lamination layer portion 3 a and the portion of the surface of the side wall part 4 b 2 (a part of the surface of the protrusion portion 4 b 21). The resin region 3 e is in contact with the side surface SF2 of the lamination layer portion 3 a and the side wall part 4 b 2 (in particular, the protrusion portion 4 b 21) and covers the side surface SF2. The intermediate layer 3 b covers the layer 3 a 3 and the resin region 3 e and is in contact with the layer 3 a 3 and the resin region 3 e.

The modification example shown in FIG. 17 will be described. FIG. 17 is a modification example of the configuration of the substrate placing table 2 in the region ER1 facing the hole GT. The substrate placing table 2 has the resin region 3 e and the insulating region 3 f as the end portion regions, and the resin region 3 g. The lamination layer portion 3 a shown in FIG. 17 has the layer 3 a 1, the adhesion layer 3 a 5 and the electrode layer 3 a 2 provided on the layer 3 a 1, and the layer 3 a 3 provided on the adhesion layer 3 a 5 and the electrode layer 3 a 2. The lamination layer portion 3 a shown in FIG. 17 does not have the adhesion layer 3 a 4 shown in FIG. 8 and the like. The layer 3 a 1 is provided on the main body part 4 a and covers the surface of the main body part 4 a. The base 4 includes the main body part 4 a and the side wall part 4 b 2 provided on the side surface of the base 4. The electrostatic chuck 3 is disposed on the main body part 4 a and the side wall part 4 b 2. The inner diameter of the layer 3 a 3 (the diameter of the region including the hole GT and defined by the side surface SF2) is smaller than the inner diameter of the main body part 4 a (the diameter of the region including the hole GT and defined by the side surface SF1). The layer 3 a 3 extends on the base 4 so as to overlap the side wall part 4 b 2. The resin region 3 g is provided between the main body part 4 a and the side wall part 4 b 2 and is in contact with the adhesion layer 3 a 5. The resin region 3 g extends so as to expand toward the lamination layer portion 3 a in the vicinity of the lamination layer portion 3 a. The resin region 3 e is in contact with the side surface SF2 of the lamination layer portion 3 a and the side wall part 4 b 2 and covers the side surface SF2. The insulating region 3 f is in contact with the side wall part 4 b 2. The resin region 3 e is disposed between the insulating region 3 f and the lamination layer portion 3 a on the side wall part 4 b 2 and is in contact with the insulating region 3 f and the lamination layer portion 3 a. The intermediate layer 3 b covers the layer 3 a 3 and the resin region 3 e and is in contact with the layer 3 a 3 and the resin region 3 e.

The modification example shown in FIG. 18 will be described. FIG. 18 is a modification example of the configuration of the substrate placing table 2 in the region ER1 facing the hole GT. The substrate placing table 2 has the resin region 3 e as the end portion region, and the resin region 3 g. The lamination layer portion 3 a shown in FIG. 18 has the layer 3 a 1, the adhesion layer 3 a 5 and the electrode layer 3 a 2 provided on the layer 3 a 1, and the layer 3 a 3 provided on the adhesion layer 3 a 5 and the electrode layer 3 a 2. The lamination layer portion 3 a shown in FIG. 18 does not have the adhesion layer 3 a 4 shown in FIG. 8 and the like. The layer 3 a 1 is provided on the main body part 4 a and covers the surface of the main body part 4 a. The base 4 includes the main body part 4 a and the side wall part 4 b 2 provided on the side surface of the base 4. The electrostatic chuck 3 is disposed on the main body part 4 a and the side wall part 4 b 2. The inner diameter of the layer 3 a 3 (the diameter of the region including the hole GT and defined by the side surface SF2) is smaller than the inner diameter of the main body part 4 a (the diameter of the region including the hole GT and defined by the side surface SF1). The layer 3 a 3 extends on the base 4 so as to overlap the side wall part 4 b 2. The resin region 3 g is provided between the main body part 4 a and the side wall part 4 b 2 and is in contact with the adhesion layer 3 a 5. The resin region 3 g extends so as to expand toward the lamination layer portion 3 a in the vicinity of the lamination layer portion 3 a. The surface of the side wall part 4 b 2 has a portion which is in contact with the lamination layer portion 3 a, and a portion extending along the side surface SF2 of the lamination layer portion 3 a (a part of the surface of the protrusion portion 4 b 21 which is included in the side wall part 4 b 2). The resin region 3 e is provided between the side surface SF2 of the lamination layer portion 3 a and the portion of the surface of the side wall part 4 b 2 (a part of the surface of the protrusion portion 4 b 21). The resin region 3 e is in contact with the side surface SF2 of the lamination layer portion 3 a and the side wall part 4 b 2 (in particular, the protrusion portion 4 b 21) and covers the side surface SF2. The intermediate layer 3 b covers the layer 3 a 3 and the resin region 3 e and is in contact with the layer 3 a 3 and the resin region 3 e.

The modification example shown in FIG. 19 will be described. FIG. 19 is a modification example of the configuration of the substrate placing table 2 in the region ER1 facing the hole GT. The substrate placing table 2 has the resin region 3 g as the end portion region. The lamination layer portion 3 a shown in FIG. 19 has the layer 3 a 1, the adhesion layer 3 a 5 and the electrode layer 3 a 2 provided on the layer 3 a 1, and the layer 3 a 3 provided on the adhesion layer 3 a 5 and the electrode layer 3 a 2. The lamination layer portion 3 a shown in FIG. 19 does not have the adhesion layer 3 a 4 shown in FIG. 8 and the like. The layer 3 a 1 is provided on the main body part 4 a and covers the surface of the main body part 4 a. The base 4 includes the main body part 4 a and the side wall part 4 b 2 provided on the side surface of the base 4. The electrostatic chuck 3 is disposed on the main body part 4 a and the side wall part 4 b 2. The inner diameter of the layer 3 a 3 (the diameter of the region including the hole GT and defined by the side surface SF2) is larger than the inner diameter of the main body part 4 a (the diameter of the region including the hole GT and defined by the side surface SF1). The layer 3 a 3 does not overlap the side wall part 4 b 2 and extends only on the main body part 4 a. The resin region 3 g is provided between the main body part 4 a and the side wall part 4 b 2, is in contact with the intermediate layer 3 b and the side surface SF2 of the lamination layer portion 3 a, and covers the side surface SF2. The resin region 3 g extends so as to expand toward the intermediate layer 3 b in the vicinity of the intermediate layer 3 b. The intermediate layer 3 b covers the layer 3 a 3, the resin region 3 g, and the side wall part 4 b 2 and is in contact with the layer 3 a 3, the resin region 3 g, and the side wall part 4 b 2.

The modification example shown in FIG. 20 will be described. FIG. 20 is a modification example of the configuration of the substrate placing table 2 in the region ER1 facing the hole GT. The substrate placing table 2 has the resin region 3 g as the end portion region. The resin region 3 g is provided between the main body part 4 a and the side wall part 4 b 2 and is in contact with the intermediate layer 3 b. The distance between the main body part 4 a and the side wall part 4 b 2 (the width of the resin region 3 g) is increased in stages toward the intermediate layer 3 b. The configuration of the substrate placing table 2 shown in FIG. 20 is different from the configuration of the substrate placing table 2 shown in FIG. 19 in terms of the distance between the main body part 4 a and the side wall part 4 b 2 (the width of the resin region 3 g) as described above.

The modification example shown in FIG. 21 will be described. FIG. 21 is a modification example of the configuration of the substrate placing table 2 in the region ER1 facing the hole GT. The configuration of the substrate placing table 2 shown in FIG. 21 has the conductive region 4 f, and the configuration of the substrate placing table 2 shown in FIG. 21 is different from the configuration of the substrate placing table 2 shown in FIG. 19 in that the conductive region 4 f is provided. The conductive region 4 f is provided on the main body part 4 a and is in contact with the main body part 4 a. The layer 3 a 1 is provided on the conductive region 4 f and is in contact with the conductive region 4 f.

The modification example shown in FIG. 22 will be described. FIG. 22 is a modification example of the configuration of the substrate placing table 2 in the region ER1 facing the hole GT. The configuration of the substrate placing table 2 shown in FIG. 22 has the conductive region 4 f, and the configuration of the substrate placing table 2 shown in FIG. 22 is different from the configuration of the substrate placing table 2 shown in FIG. 20 in that the conductive region 4 f is provided. The conductive region 4 f is provided on the main body part 4 a and is in contact with the main body part 4 a. The layer 3 a 1 is provided on the conductive region 4 f and is in contact with the main body part 4 a and the conductive region 4 f.

The configuration shown in each of FIGS. 21 and 22 in which the conductive region 4 f is provided is also the same in FIGS. 15 to 18.

The modification example shown in FIG. 23 will be described. FIG. 23 is a modification example of the configuration of the substrate placing table 2 in the region ER1. In the configuration of the substrate placing table 2 shown in FIG. 23, a recessed portion 4 a 1 is provided on the surface of the main body part 4 a. The conductive region 4 f, the lamination layer portion 3 a, and the resin region 3 e are provided in the recessed portion 4 a 1. The lamination layer portion 3 a shown in FIG. 23 has the layer 3 a 1, the adhesion layer 3 a 5 and the electrode layer 3 a 2 provided on the layer 3 a 1, and the layer 3 a 3 provided on the adhesion layer 3 a 5 and the electrode layer 3 a 2. The lamination layer portion 3 a shown in FIG. 23 does not have the adhesion layer 3 a 4 shown in FIG. 8 and the like. The layer 3 a 1 is provided on the conductive region 4 f. The electrode layer 3 a 2, the adhesion layer 3 a 5, the layer 3 a 3, and the resin region 3 e are provided on the layer 3 a 1. The resin region 3 e is in contact with the layer 3 a 1 and the side surface SF2 of the lamination layer portion 3 a and covers the side surface SF2. The intermediate layer 3 b covers the layer 3 a 3, the resin region 3 e, and the main body part 4 a and is in contact with the layer 3 a 3, the resin region 3 e, and the main body part 4 a.

The modification example shown in FIG. 24 will be described. FIG. 24 is a modification example of the configuration of the substrate placing table 2 in the region ER1. In the configuration of the substrate placing table 2 shown in FIG. 24, the conductive region 4 f is provided on the main body part 4 a, and the lamination layer portion 3 a is provided on the conductive region 4 f. The lamination layer portion 3 a shown in FIG. 24 has the layer 3 a 1, the adhesion layer 3 a 5 and the electrode layer 3 a 2 provided on the layer 3 a 1, and the layer 3 a 3 provided on the adhesion layer 3 a 5 and the electrode layer 3 a 2. The lamination layer portion 3 a shown in FIG. 24 does not have the adhesion layer 3 a 4 shown in FIG. 8 and the like. The layer 3 a 1 is provided on the conductive region 4 f. The resin region 3 e is provided on the main body part 4 a, is in contact with the main body part 4 a, the side surface SF2 of the lamination layer portion 3 a, and the side surface of the conductive region 4 f, covers the side surface SF2 and the side surface of the conductive region 4 f, and has a tapered shape that is tapered in a direction separated from the lamination layer portion 3 a. The intermediate layer 3 b covers the layer 3 a 3, the resin region 3 e, and the main body part 4 a and is in contact with the layer 3 a 3, the resin region 3 e, and the main body part 4 a.

In the substrate placing table 2 having the configuration shown in each of FIGS. 8 to 24 described above, the side surface SF2 of the electrostatic chuck 3 is covered with the resin region 3 e made of a material having a relatively high viscosity and the resin region 3 e is cured, or the side surface SF2 of the electrostatic chuck 3 is covered with the insulating region 3 f. Therefore, the occurrence of cracks or the like in the intermediate layer 3 b and the covering layer 3 c covering the resin region 3 e or the insulating region 3 f whose shape is maintained is suppressed, and both the intermediate layer 3 b and the covering layer 3 c can be formed in a good shape together with the configuration of the side surface SF2 of the electrostatic chuck 3 (the resin region 3 e or the insulating region 3 f).

According to an exemplary embodiment, a technique for suppressing an electric discharge between the substrate placing table and the substrate can be provided.

Although various exemplary embodiments have been described above, various modified aspect may be configured without being limited to the above-described exemplary embodiments.

While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the disclosures. Indeed, the embodiments described herein may be embodied in a variety of other forms. Furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the disclosures. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the disclosures. 

What is claimed is:
 1. A substrate support comprising: a base; and an electrostatic chuck disposed on the base, the electrostatic chuck including: a stack disposed on the base, the stack having an upper face and a side face, the stack including a first insulation layer, a second insulation layer, and an electrode layer disposed between the first insulation layer and the second insulation layer, the electrode layer being covered by one or both of the first insulation layer and the second insulation layer; a first cover layer covering the upper face and the side face of the stack; and a second cover layer covering the first cover layer, the second cover layer comprising ceramic material.
 2. The substrate support according to claim 1, wherein the first cover layer has an annular portion surrounding the side face of the stack, and the annular portion has a lower face contacting the base.
 3. The substrate support according to claim 2, wherein the annular portion has a first inclined face above the lower face.
 4. The substrate support according to claim 3, wherein the second cover layer has a second inclined face along the first inclined face.
 5. The substrate support according to claim 3, wherein the first inclined face is inclined by 45 degrees or less to the lower face.
 6. The substrate support according to claim 2, wherein the annular portion has a first curved face above the lower face.
 7. The substrate support according to claim 6, wherein the second cover layer has a second curved face along the first curved face.
 8. The substrate support according to claim 2, wherein the stack has a first adhesion layer disposed between the first insulation layer and the base.
 9. The substrate support according to claim 8, wherein the stack has a second adhesion layer disposed between the second insulation layer and the first cover layer.
 10. The substrate support according to claim 1, wherein the stack has a second adhesion layer disposed between the second insulation layer and the first cover layer.
 11. The substrate support according to claim 1, wherein the first insulation layer comprises a ceramic material, or a resin material selected from the group consisting of polyimide, silicone, epoxy and acrylic resins.
 12. The substrate support according to claim 11, wherein the second insulation layer comprises a resin material selected from the group consisting of polyimide, silicone, epoxy and acrylic resins.
 13. The substrate support according to claim 1, wherein the first cover layer comprises a base material and a particulate material dispersed in the base material, and at least part of the particulate material is in contact with the second insulation layer and the upper face of the stack.
 14. The substrate support according to claim 13, wherein the base material comprises a silicone resin and the particulate material comprises a ceramic material.
 15. A plasma processing apparatus comprising: a plasma processing chamber; a substrate support disposed in the plasma processing chamber, the substrate support comprising: a base; and an electrostatic chuck disposed on the base, the electrostatic chuck including: a stack disposed on the base, the stack having an upper face and a side face, the stack including a first insulation layer, a second insulation layer, and an electrode layer disposed between the first insulation layer and the second insulation layer, the electrode layer being covered by one or both of the first insulation layer and the second insulation layer; a first cover layer covering the upper face and the side face of the stack; and a second cover layer covering the first cover layer, the second cover layer comprising a ceramic material; and a RF power source electrically connected to the substrate support.
 16. The plasma processing apparatus according to claim 15, wherein the RF power source is configured to generate a RF power having a frequency of 3 MHz or less.
 17. The plasma processing apparatus according to claim 15, wherein the RF power source is electrically connected to the base. 